Comparative study of nano-sized particles CoFe2O4 effects on superconducting properties of Y-123 and Y-358
Identifieur interne : 000026 ( France/Analysis ); précédent : 000025; suivant : 000027Comparative study of nano-sized particles CoFe2O4 effects on superconducting properties of Y-123 and Y-358
Auteurs : Y. Slimani [Tunisie] ; E. Hannachi [Tunisie] ; M. K. Ben Salem [Tunisie] ; A. Hamrita [Tunisie] ; A. Varilci [Turquie] ; W. Dachraoui [France] ; M. Ben Salema [Tunisie] ; F. Ben Azzouz [Tunisie, Arabie saoudite]Source :
- Physica. B, Condensed matter [ 0921-4526 ] ; 2014.
Descripteurs français
- Pascal (Inist)
- Transition supraconductrice, Conductivité électrique, Réaction état solide, Microstructure, Diffraction RX, Microscopie électronique balayage, Paramètre cristallin, Grosseur grain, Site impureté, Stoechiométrie, Nanoparticule, Cobalt Fer Oxyde Mixte, Supraconducteur haute température, Baryum Cuivre Yttrium Oxyde Mixte, Polycristal, Nanocomposite, CoFe2O4, Ferrite de cobalt, Cuprate d'yttrium et de baryum, Y3Ba5Cu8O18, YBa2Cu3O7.
English descriptors
- KwdEn :
- Barium Copper Yttrium Oxides Mixed, Cobalt Iron Oxides Mixed, Electrical conductivity, Grain size, High-Tc superconductors, Impurity site, Lattice parameters, Microstructure, Nanocomposites, Nanoparticles, Polycrystals, Scanning electron microscopy, Solid state reaction, Stoichiometry, Superconducting transitions, XRD.
Abstract
The effects of nano-sized CoFe2O4 particles (10 nm) addition on the structural and the normal state resistivity of YBa2Cu3O7 (noted Y-123) and Y3Ba5Cu8O18 (noted Y-358) polycrystalline were systematically studied. Samples were synthesized in oxygen atmosphere using a standard solid state reaction technique by adding CoFe2O4 up to 2 wt%. Phases, microstructure and superconductivity have been systematically investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM) and electrical measurements ρ(T). XRD results reveal that the lattice parameters change for both Y-123 and Y-358 phases. SEM observations reveal that the grain size is reduced with increasing the content of CoFe2O4. The measurements for the resistivity dependence of temperature show that the depression in superconducting temperature is more pronounced for CoFe2O4 addition in Y-358 compound than in Y-123 one. These results may be attributed to the existence of much more disorder due to a greater number of Cu sites to be substituted by Fe and Co in Y-358 compared to Y-123.
Affiliations:
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Pascal:14-0214453Le document en format XML
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O<sub>4</sub>
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<series><title level="j" type="main">Physica. B, Condensed matter</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Barium Copper Yttrium Oxides Mixed</term>
<term>Cobalt Iron Oxides Mixed</term>
<term>Electrical conductivity</term>
<term>Grain size</term>
<term>High-Tc superconductors</term>
<term>Impurity site</term>
<term>Lattice parameters</term>
<term>Microstructure</term>
<term>Nanocomposites</term>
<term>Nanoparticles</term>
<term>Polycrystals</term>
<term>Scanning electron microscopy</term>
<term>Solid state reaction</term>
<term>Stoichiometry</term>
<term>Superconducting transitions</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Transition supraconductrice</term>
<term>Conductivité électrique</term>
<term>Réaction état solide</term>
<term>Microstructure</term>
<term>Diffraction RX</term>
<term>Microscopie électronique balayage</term>
<term>Paramètre cristallin</term>
<term>Grosseur grain</term>
<term>Site impureté</term>
<term>Stoechiométrie</term>
<term>Nanoparticule</term>
<term>Cobalt Fer Oxyde Mixte</term>
<term>Supraconducteur haute température</term>
<term>Baryum Cuivre Yttrium Oxyde Mixte</term>
<term>Polycristal</term>
<term>Nanocomposite</term>
<term>CoFe2O4</term>
<term>Ferrite de cobalt</term>
<term>Cuprate d'yttrium et de baryum</term>
<term>Y3Ba5Cu8O18</term>
<term>YBa2Cu3O7</term>
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<front><div type="abstract" xml:lang="en">The effects of nano-sized CoFe<sub>2</sub>
O<sub>4</sub>
particles (10 nm) addition on the structural and the normal state resistivity of YBa<sub>2</sub>
Cu<sub>3</sub>
O<sub>7</sub>
(noted Y-123) and Y<sub>3</sub>
Ba<sub>5</sub>
Cu<sub>8</sub>
O<sub>18</sub>
(noted Y-358) polycrystalline were systematically studied. Samples were synthesized in oxygen atmosphere using a standard solid state reaction technique by adding CoFe<sub>2</sub>
O<sub>4</sub>
up to 2 wt%. Phases, microstructure and superconductivity have been systematically investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM) and electrical measurements ρ(T). XRD results reveal that the lattice parameters change for both Y-123 and Y-358 phases. SEM observations reveal that the grain size is reduced with increasing the content of CoFe<sub>2</sub>
O<sub>4</sub>
. The measurements for the resistivity dependence of temperature show that the depression in superconducting temperature is more pronounced for CoFe<sub>2</sub>
O<sub>4</sub>
addition in Y-358 compound than in Y-123 one. These results may be attributed to the existence of much more disorder due to a greater number of Cu sites to be substituted by Fe and Co in Y-358 compared to Y-123.</div>
</front>
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